Thanks for that chaps - couple more things:
1 - Reviewed the piston movement (agreed, its the pistons moving not the cylinders lol). Actually, the nearside piston moves but the farside piston isnt moving (though it was earlier on during the day). One cylinder is new, the other is old and its the old cylinder that is moving fine.
It appears that the new brake pipes route to the first cylinder and then from the first cylinder to the second cylinder. I've attached a pic below showing what I think is the second cylinder's bleed nipple, is this correct?
The cylinders are shown below (the older looking one is moving 5-6mm and moves the shoe 2-4mm, whereas the newer cylinder (the first one in the chain of the brake pipes) isn't moving now.
Pic before piston moved......and after moving

In terms of the master cylinder and brake pedal, the pistons only move when the brake pedal is right to the floor and it really doesnt feel like theres any pressure behind it (i've been pressing it with my hand and its very weak).
Also, we've been searching for rust and the only major rust we've found is round the inner rear arches - see below. Whilst this is going to get sorted anyway, is this likely to be an MOT failure point (as we're going to get it MOT'd before we do any major bodywork bits on it as much as possible).
