The V8 forum guys are a bit stumped on why it happened too - never seen it happen.
Thread in V8 forum:
http://www.v-8.org.uk/forum/viewtopic.php?t=524
Check out the pics:
Before I started

One off

No 1 N/S

No 4 N/S

No 2 N/S - undamaged

Pistons

No 1 N/S

Head

Casting Number of 'Vitesse' head

Casting number of my spare SD1 head

The 3 heads - Vitesse, SD1 and P6 - left to right

Vitesse and SD1 head - note combustion chamber difference


SD1 and P6 head - similar combustion chambers:

Close ups of combustion chambers:
Vitesse

SD1

P6

I think that the 'Vitesse' heads had a much smaller combustion chamber, causing massive detonation, but then, why not on all cylinders. Engine was never overheated and wasn't driven - still a mystery to me.
I'm going to build up a spare SD1 engine I have, use the new valves and springs from the damaged head, and the cam from the P6 engine and see how that goes - unless someone has another suggestion.
Pete